Confusing matrix elements
When we discuss about the matrix element of optical transition, we often can use either of the following ways:1) H1=exE, where e is the electronic charge, E is the electric field
2) H1=epA/m, where p is the momentum of the electron and A is the vector potential.
Following approach 1):
transition rate:
W=|<φi|exE0|φf>|2 δ(Ei-Ef-ħω)=e2E02|<φi|x|φf>|2δ(Ei-Ef-ħω)
Power:
P=ħωe2E02|<φi|x|φf>|2δ(Ei-Ef-ħω)
Dielectric constant (imaginary part):
ε2=P/(ε0ωE02)=ħe2/ε0|<φi|x|φf>|2δ(Ei-Ef-ħω)
However, if we use the approach 2)
transition rate:
W=|<φi|epA/m|φf>|2 δ(Ei-Ef-ħω)=(e/m)2A02|<φi|p|φf>|2δ(Ei-Ef-ħω)
Power:
P=ħω(e/m)2A02|<φi|p|φf>|2δ(Ei-Ef-ħω)
Dielectric constant (imaginary part):
using the relation that E0=iωA0
ε2=P/(ε0ωE02)=ħ(e/m)2/(ε0ω2)|<φi|p|φf>|2δ(Ei-Ef-ħω)
We can easily see that the function ε2(ω) in the two cases are very different, which one is correct and why?
In all the books I read, approach 2) seems to be used, why?
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