Monday, June 30, 2008

Confusing matrix elements

When we discuss about the matrix element of optical transition, we often can use either of the following ways:

1) H1=exE, where e is the electronic charge, E is the electric field
2) H1=epA/m, where p is the momentum of the electron and A is the vector potential.

Following approach 1):

transition rate:
W=|<φi|exE0f>|2 δ(Ei-Ef-
ħω)=e2E02|<φi|x|φf>|2δ(Ei-Ef-ħω)

Power:
P=
ħωe2E02|<φi|x|φf>|2δ(Ei-Ef-ħω)

Dielectric constant (imaginary part):
ε2=P/(ε0ωE02)=ħe20|<φi|x|φf>|2δ(Ei-Ef-ħω)

However, if we use the approach 2)

transition rate:
W=|<φi|
epA/mf>|2 δ(Ei-Ef-ħω)=(e/m)2A02|<φi|p|φf>|2δ(Ei-Ef-ħω)

Power:
P=
ħω(e/m)2A02|<φi|p|φf>|2δ(Ei-Ef-ħω)

Dielectric constant (imaginary part):
using the relation that E0=
iωA0
ε2=P/(ε0ωE02)=ħ(e/m)2/(ε0ω2)|<φi|p|φf>|2δ(Ei-Ef-ħω)

We can easily see that the
function ε2(ω) in the two cases are very different, which one is correct and why?

In all the books I read, approach 2) seems to be used, why?

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